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When performing a Merge-to-PDF with a Word template pulling data from Excel, is it possible to have the results of the merge combined into a single document rather than separate PDF documents?
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Use the Combine Files feature in Acrobat.
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Yes, but if the merged files contain form fields you'll need to flatten them first.
If you're interested, I've developed a (paid-for) tool that will perform a Mail Merge and then join the file automatically for you (or not, if you prefer them to remain separate). You can find it here:
https://www.try67.com/tool/acrobat-mail-merge-and-email-pdf-files