This user posted a few weeks back about a similar issue and found it was related to a Windows setting. I wondered if this might be the same cause in your case, too. https://adobe.ly/3VGW4XE Could you please check and see if it helps?
/t5/adobe-express-bugs/the-color-picker-doesnt-pick-the-right-colour/idc-p/15092157#M24490Jan 15, 2025
Jan 15, 2025
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I am having this issue, and the Windows setting did not help me. I have posted to the Facebook Adobe Express Insiders group a couple videos of this happening. It is basically producing a a darker color and tone.
/t5/adobe-express-bugs/the-color-picker-doesnt-pick-the-right-colour/idc-p/15151183#M24957Feb 13, 2025
Feb 13, 2025
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Hey @brandon_4545, welcome to Adobe Express Community!! I tried to replicate the issue, but it worked fine for me. Can you please share the workflow video and the image from which the color will be picked for us to test and investigate?