Sorry to hear you are unable to use the "Edit in Photoshop" option in XD. I am unable to reproduce the issue at my end on my windows machine. Does that happen with every file or with this specific file? Have you tried using the function in a new file and share results with us? Please try using a different image and see if that works. I would also suggest selecting the image from the layer panel and then use "Edit in Photoshop".