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For something like this, you might be best off rotoscoping the shot, i.e. manually keyframing a mask.
1) Create a mask and animate it around your water droplet.
2) Apply an effect to desaturate your clip.
3) Twirl the effect open in the timeline (you can also double-click the effect name in the Effects Control panel).
4) Twirl open Compositing Options.
5) Click the + button.
6) Choose your mask. This will then mask your effect so only the water droplet will be desaturated.
7) On the mask, click the Invert button or change the mode to Subtract so the droplet is in color and the rest of the shot is desaturated.
8) Feather the mask a little to add the small halo you mentioned.