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I can't synchronize a folder on the desktop of Creative Cloud. I don't know what the problem
We can't know, either. You have not provided any proper system information or other technical details.
File Sync Links that may help... all the links I have, since I don't know your specific problem
-Size Limits https://forums.adobe.com/thread/1488242
-sync and email link http://forums.adobe.com/thread/1427516?tstart=0
-Phantom folder problem https://forums.adobe.com/thread/1490445