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Is it possible to set up an entire corporate approval process - including requisitions, purchase orders and supplier invoices - plus quotations, negotiations and invoices to customers - using Adobe products?
This sounds like a job for Adobe Document Cloud. You could investigate Adobe Sign. It has some excellent document workflow and signature capabilities.
For a true enterprise-class solution, Adobe AEM Forms can be used as well. However, it'll require a fair amount of investment in terms of implementation as per your requirements.