I see two scenarios-
1) If you have Lightroom-Classic set to Sync- then all files in Lightroom will be automatically downloading into the LrC catalog. You would only need to locate them in the LrC catalog to 'Edit in' Photoshop.
A good hint is to set the Folder of your choosing for all Lightroom downloads in LrC preferences. SYNC SETUP IN CLASSIC
2) If you are not syncing LrC to Lightroom- Export the files from Lightroom (Original + edits), 'Open' immediately in Photoshop.
Regards. My System: Lr-Classic 12.2 Photoshop 24.2, ACR 15.2, Lightroom 6.2, Lr-iOS 8.0.8, Bridge 13.0.2, Windows-11.