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When picture is taken with Nikon Z6, background is dead white and displays so on playback on the camera. White balance is set to Auto natural light.
When imported into Lightroom classic the background is gray. Other colors in the photo appear close to true.
Monitor is regularly calibrated with Spyder 5.0.
Your white is gray because the image is under exposed. Check the image histogram and you'll see the problem in all its glory.