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It was working fine yesterday, but for some reason I suddenly can't pick my saved colors from th libraries, not even the pre installed ones. Has anyone else had this problem? if so is there a way to fix this?
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Let's make sure we're in a default state and there are no stale settings somewhere:
Restore your preferences using this manual method:
https://helpx.adobe.com/photoshop/using/preferences.html#Manually 
Does it work correctly?
If that doesn't solve it, you can quit Photoshop and put the Settings folder back.
It may help if we could see your Photoshop System Info. Launch Photoshop, and select Help >System Info...and copy/paste the text in a reply.