I did look at the previous similar topic and I did go to file handling and change "recent file list" to 5 from 20. I also went to Edit, Purge, purge all ...
If I merge all layers then save PSD it will save in a fraction of a second. If I attempt to save with multiple layers (even just as few as 3) it will freeze at 99%. I opened a different file and created just a couple of dupicate layers and attempted to save as PSD. It did the same thing, freezing at 99%.
I am running a newer I9 system with 64 gig of RAM and multiple terabytes of disk space available.