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If I have a PSD containing more than roughly 75 smart objects, if I try to save a copy of the document as a PNG, it saves an uncompressed version of the image and ignores your PNG compression settings.
Photoshop since at least the 2021 CC version, Windows 10.
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Note that using the Quick Export as PNG feature compresses images as intended.
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When you Save As, it includes all metadata, Quick Export doesn't.
Just to rule out excessive metadata, what do you see if you go to File > File Info > Raw Data on the PNG Save As version?