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both are in the RGB color space—why is the color of the artwork changing so much? I get the same result no matter how I bring the artwork into Photoshop.
I used transparency flattener in illustrator first before bringing the artwork into Photoshop and that fixed the colors.
What color profiles are you using in each?
I would go into Adobe Bridge>Edit Menu>Color Settings and make sure that:
1. The color profile is synced
2. If not, choose a color profile and apply.
3. Double check settings in PS and AI to make sure they match and are not converting when going between the two.