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Can I have PSE organizer automatically move 5 star images into a designated 5 star album?
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Use the Organizer menu:
Find > By Details (metadata)
Whilst this is a search function it is effectively a dynamic album which updates each time you run the search from the same menu:
Find > By Saved Searches
You could select all the results (Ctrl+A) to make a physical album.
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. . . or you can simply use the Equal to star rating filter. If you want the ability to sort the images to an Album Order, then you will have to do as John says and add the images to a new Album, manually.