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I currently have PSE18 on my older laptop. Will PSE18 work on Window 11?
Since it works on Windows 10, I would expect it to work on Windows 11.
I know PSE 2020 works on Windows 11.
It's not a configuration which is officially supported by Adobe. All you can do is try it.
Having said that, it should run OK but any issues you encounter will be up to you to fix - or you can ask in these Community Forums.