Which version of PSE are you using? There are several ways to do this, e.g. feathering a selection when using the magnetic lasso tool, or with a mask, etc.
In PSE2024, when you open the Guided edit tab in the editor, there is a Vignette effect wish may be suitable for your purpose.
It would help if you post the picture here on the forum. This will help us to provide more targeted suggestions.
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