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If they want a .scc file, pick the .scc sidecar file options.
Youtube and Vimeo do not automatically pick up the sidecar file. You must go into subtitles and add it.
I assume you are trying to send to Youtube/Vimeo to test it, but their method of using the sidecar file may be different from the player used by the broadcaster.
There are some gotchas in terms of whether PR will export the sdiecar with the correct zero point timecode.