Yes. You will have to install the 32bit MSCCI-provider to make it work. After that it is a walk in the park.
Here are the steps you have to follow to set it up: http://www.adobe.com/devnet/robohelp/articles/robohelp-tfs-integration.html
The article is somewhat old, but the steps are the same for VS2013.
Thanks, @William van Weelden.