I think you'll really like Photoshop CS6. I have it, and I enjoy using several of the new features. But I also use Lightroom, and use it more extensively than I use Photoshop. Eventually, when the next version of Photoshop is released, I'm going to have to deal with the differences in Camera Raw. And isn't going to bother me at all. I have dealt with it in the past, it is simple, and I'm satisfied with the results. But I would never want to be without Photoshop for those times when I need it. I think you are making a good choice.
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