Syncronized colors still don't match?

I started this question in the illustrator forums, but couldn't figure out an answer. I was told to relay the info here.

Original Discussion:

Exported Colors don't match Preview Colors - RGB

My Problem:

Colors don't match in different adobe programs (even though color settings are synced, color modes are the same, and they are being viewed on the same monitor).

This video displays my problem, although it shows older info than the images below (You may need to use the chrome browser if you aren't already):

Color_Problems.mp4 - Google Drive

These images show the details (I shared these after I made the video, so the info is more updated)

Photoshop color settings:

Illustrator color settings:

Any ideas? Why aren't the colors the same?