Whenever the illustrator is turned on and the color picker is checked, the default value is not set to white black, but to white and dark gray. For your information, I am using the 2022 version, and I am not experiencing any other problems with colors.
It is probably because your RGB document once started as a CMYK document.
The values of the colors in your swatches panel are cmyk values converted to rgb.
Just create RGB documents based on RGB presets, like Art & Illustration.
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