Changing CMYK to spot colors for a "color library" effect
Hello,
I have some photos that are going to get printed. I'm experimenting with color and I'm trying to replicate the "https://colorlibrary.ch/ " effect. I want to keep the four channels (c m y k), but changing the cyan, magenta... inks with spot colors. It should be simple, but I can't manage to do it.

This should be the process I'm trying to follow but, when i try to do the second step, "channel options" is grayed out, and I don't know how to continue.
I feel so stupid ahaha, I hope someone is able to help me! Thank you in advance.