
Hi
The effect that you are seeing against the black mask is there in the original image so is not really a shortcoming of the mask.
Your original at 100% zoom shows these very light grey edge pixels

Using "Select Subject" is including those pixels in the "wanted" area

Using Shift edge takes them out


At 100% zoom, after shifting the edge:

If you want to continue and take out the reflection from the white background on the surface of the material, add a new layer and clip it to the masked coat layer (Alt-Click on border netween the two in the layers panel). Set the blending mode to Darker Colour and use a soft brush to pick up colour from the coat and brush over those light reflections.


Dave