This worked with my Brother 5200DW
- CONTROL PANEL > PRINTERS > RIGHT CLICK YOUR PRINTER.
- Choose PRINTER PROPERTIES (not to be confused with 'printer preferences', or 'properties' at bottom).
- Choose the Tab 'DEVICE SETTINGS'
- Under 'INSTALLABLE OPTIONS' section is a line item 'DUPLEX SETTINGS'. Change it to INSTALLED.
- Click APPLY.
I reopened my PDF and the option was available under the PAGE HANDLING AND SIZING section of the dialog box.
As I said, this worked for me. But, I did find one other option having to do with double sided printing. It likely has the correct setting, but if not, there is an option to flip on the long edge or short edge. Go into Control Panel > Printers >right click your printer > choose Printer Preferences, under 'Print on both sides of paper' there is a drop down options box.