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I can not open the file .7z to instal Photoshop CS6
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you should not manually extract that archive.
download the matching exe (the extractor) and place it in the same directory as your 7z (archive). click, or double click, the exe.
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Download and installation help for Adobe links
Download and installation help for Prodesigntools links are listed on most linked pages. They are critical; especially steps 1, 2 and 3. If you click a link that does not have those steps listed, open a second window using the Lightroom 3 link to see those 'Important Instructions'.