Adding colour

The fourth tool from the top in the left tool bar is the magic want. It selects all of one color. Use that tool and click on any black area. There is also an option at the top, after you pick the magic want, to select continguous. With that checked, the tool will only select black that it is touching. If you un-select Continugous, then it will select the black on the entire document. Once you do that the marching ants wil appear all around the black. Now you can pick any color you want. Once you select the color, change the tool to the paint bucket and then you can click anywhere inside the marching ants and the entire area will change colors. 

One note: before you click to change the color with the paint bucket, you might want to create a new layer by clicking Shift-Command-N (that is for a mac) or in the layers panel you can click the three small lines in the upper right corner and the first option is New Layer. You can name it if you want or just hit Ok and THEN spill the new color with the paint bucket.