Hi there,
As you want to smoothen out the edges, please follow the steps below and see if it helps.
1. Make a selection using any of the selection tools ( I use quick selection and click on the area to create a selection).
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2. Then click on Select & Mask on top to open up a new panel and increase the smooth slider values by dragging the slider to the right.
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3. Then hit CTRL + D (Windows) OR CMD +D (macOS) to remove the selection.
Let us know if it helps.
Regards,
Sahil