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I have nine 8x10 family pictures. Mount on a 10x10 canvas collage.
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Ideally you want to keep each image on it's own layer as shown in my screenshot below. That will give the freedom to resize and transform images separately.
Nancy
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There is no automatic way to do this with Photoshop. Follow Nancy OShea's directions to manually build your collage. I would start with a new document 10"x10" at 200 ppi.