Why the hell I have receiving code 224 on my PS when I paid my subscription Annually?

check your account, https://account.adobe.com 

does that show your subscription with no payment problem.?

if so, sign out and then sign back into your cc desktop app using the same username and password used to confirm your subscription.

Check out the following article, it may help

https://helpx.adobe.com/download-install/apps/troubleshoot/error-codes-1-99/error24.html