Can I have a personal cloud storage accound and a work-related CC account?

Hello. 

I use the same computers for corporate and personal use. 

I have a corporate account for Creative Cloud. That gives me access to the applciations I use regularly for work. 

I also use Lightroom for personal use. I'd like to use Cloud Storage for personal photography.

I would like to keep my personal photographs on cloud storage, and pay for upgraded cloud storage. 

Can I use the professional account for the software, and a personal account for cloud storage, at the same time?

Thank you.