Hey, @robtl. Welcome to the Lightroom Community. I'll need more info to help you figure this out. Please share the version of Lightroom & operating system you are working on. Do you see an error or pop-up? Please share more details, like screenshots or video recordings of what you see.
Go to the following location to launch Photoshop via terminal In Finder > Application Folder > Adobe Lightroom > Right-click on Lightroom.app > Show Package Contents > Contents > macOS > Lightroom - double click to open.
If Lightroom does not launch, look at the terminal window and copy & share the results with us here.