Page 79, by the late, great Bruce Fraser explains this in his Camera Raw with CS2 book (an oldie but a goodie everyone need s to read):
"Temperature. The Temperature control lets you specify the color temperature of the lighting in Kevins, thereby setting the blue-yellow (not orange) color balance. Lowering the color temperature makes the image more blue to compensate for the yellower light; raising the color temperature makes the image more yellow, to compensate for the bluer light. If this seems counterintutive - we think of higher color temperature as bluer and lower one's as yellower- the trick is to remember that the Temperature control compensates for the color temperature of the light, so if you tell Camera Raw that the light is bluer, it makes the image yellower."
Author “Color Management for Photographers" & "Photoshop CC Color Management/pluralsight"