Would like to get into Enterprise Licensing, but can't figure out how to get started.
You didn't mention the products or services that you're interested in. I'm assuming that you're looking for Creative Cloud for enterprise. https://www.adobe.com/creativecloud/business/enterprise.html
Also see this page for an overview of the Buying Programs at https://www.adobe.com/howtobuy/buying-programs/enterprise.html. You can also reach out to the Sales team and request a consultation. The team will understand your requirements and recommend solutions that best meets your needs.
In case you think that Enterprise doesn't meet your requirements, you can also consider Creative Cloud for teams, which adresses the needs of small and medium businesses. You can purcahse a plan directly from: https://www.adobe.com/creativecloud/business/teams.html
Hope this helps.