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I have photoshop installed on my machine and never use PSE as an editor. I do not know why LR switched from PS to PSE as an editor, but I cannot figure out how to permanently remove it without deleting the software from my computer.
Right now it defaults to PSE, so if I want to open it as a smart object in PS, it opens it in PSE.
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Try A reinstall Of Photoshop, to change.
Uninstall then reinstall Photoshop 2022 from your Adobe Creative Cloud Desktop App.
This suggestion is "Solution 1" at-
https://helpx.adobe.com/lightroom-classic/kb/edit-photoshop-command-missing-photoshop.html
You could also try "Solution 2" if you are confident to edit the Windows Registry.