Sorting by capture date (old to new) displays the oldest photo as the last one. This is logical and convenient. Calendars work this way, it is a natural way of viewing content.
The problem is that when you open LR, be it Desctop, mobile or Apple TV, the firs photo is displayed / selected. This is the oldest photo in the library. It would be much better to be presented with your latest photos. Your newest photo should be selected, and should be positioned at the bottom.