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The results the Neural Filter »Smart Portrait« provides are, in my opinion, not good enough so far and this photograph is not a good basis anway (glasses, the hair, …) so I would recommend looking for (or taking) a more »fitting« photograph.
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Though if you meant the angle on the axis perpendicular to the image plane a »simple« Transform/Warp with some Masking and Decontaminating might suffice.