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Is there a Photoshop Quick Reference Guide that tells what each of the items are on the left side of the workspace? (And for other tools in Creative Cloud).
Try this: https://helpx.adobe.com/photoshop/using/tools.html
This is perfect- thank you!
You can also turn on Rich Tool Tips in Preferences > Tools.
You'll find it too intrusive once you get used to things, but as an experienced user I still work with Show Tool Tips turned on. This will bring up a tool's name when you hover the cursor over it.
Another super useful resource is Discover which you bring up with the search icon in the top right corner.