Hi @JamstaGrafix,
Thank you for sharing the screenshot and your observations. I have checked this in Illustrator 29.3 and the latest 29.7 on Windows, and the alignment in the New Document panel appears fine here. Could you please confirm the exact Illustrator version and your OS?
Meanwhile, you can try resetting the UI to see if it resolves the issue. To do this, first close Illustrator and rename the following folders:
• Rename the CEP folder to CEP.old
Mac: /Library/Application Support/Adobe
Windows: C:\Program Files (x86)\Common Files\Adobe
• If that doesn't help, rename the UXP folder to UXP.old
Mac: /Library/Application Support/Adobe and ~/Library/Application Support/Adobe
Windows: C:\Program Files\Common Files\Adobe and C:\Program Files (x86)\Common Files\Adobe
Once renamed, relaunch Illustrator and check if the alignment appears correctly.
Kindly give this a try and let me know the outcome.
Looking forward to your update.
Abhishek