Digital painting - check out Bert Monroy - he's amazing and a great guy: Bert Monroy Photoshop is a tool, like a hammer or a screwdriver. You bring your skills along to use it, those skills might be artist, painter, designer, photographer, etc. A matte painter who used Photoshop is probably proficient with real life painting using oils and acrylics. Like Barb said, you need to master the basics and I'll toss in masking as the next step.
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